Tapioca Starch (Best Option)
1:1 (use equal amount to arrowroot powder)Tapioca starch is a fine, neutral-tasting starch that gelatinizes at a similar temperature to arrowroot powder, providing thickening and moisture retention in brownie batter. It helps create the characteristic fudgy and glossy texture by binding water and fats effectively.
When substituting, use the same amount as arrowroot powder. Mix it well with dry ingredients to avoid clumping. Be mindful not to overbake, as tapioca starch can make the brownies slightly more elastic if exposed to prolonged heat.
Compared to arrowroot powder, tapioca starch produces brownies with a very similar chew and shine, making it the closest functional and sensory match.