Baking Soda and Cream of Tartar (Best Option)
1/4 teaspoon baking soda + 1/2 teaspoon cream of tartar per 1 teaspoon baking powderBaking powder is essentially a combination of baking soda (a base) and an acid (often cream of tartar). By mixing baking soda with cream of tartar, you recreate the chemical leavening reaction that produces carbon dioxide gas, which helps the brownies rise and develop a tender crumb.
To ensure success, measure both components accurately and mix them thoroughly into the dry ingredients to avoid uneven leavening. Avoid adding extra acidic ingredients that could disrupt the balance.
Compared to commercial baking powder, this substitute provides nearly identical leavening and texture, preserving the fudgy yet slightly airy quality typical of brownies.