White Vinegar (Best Option)
1 teaspoon per 1 tablespoon lemon juiceWhite vinegar is a clear, mild acid that effectively reacts with baking soda to produce carbon dioxide, which helps biscuits rise and develop a tender crumb. Its neutral flavor profile ensures it doesn't compete with the buttery or savory notes typical in biscuits.
When substituting, use slightly less white vinegar than lemon juice to avoid an overly sharp taste. Mix thoroughly into the wet ingredients to ensure even acid distribution.
Compared to lemon juice, white vinegar preserves the biscuit's texture and rise without adding citrus flavor, making it the most reliable acid substitute in biscuit recipes.