Lemon Juice (Best Option)
1 tablespoon per 1 tablespoon of white vinegarLemon juice works well as a substitute because it has a comparable acidity level (pH around 2-3) to white vinegar, which helps to cut through the richness of the meat and potatoes in Shepherd's Pie. The citric acid in lemon juice also aids in tenderizing the meat slightly and enhancing the overall flavor complexity.
When using lemon juice, ensure it is fresh to avoid any bitter or off-flavors. Add it gradually and taste as you go to maintain the desired acidity without overwhelming the dish with citrus notes.
Compared to white vinegar, lemon juice imparts a slightly brighter and fresher flavor, which can enhance the dish's appeal without detracting from its traditional savory character.