Baking Soda and Vinegar (Best Option)
1/4 teaspoon baking soda + 1/2 teaspoon vinegar per 1 cup flourBaking soda is a base that reacts with acids like vinegar to produce carbon dioxide gas, which leavens the dough quickly. This reaction mimics the leavening effect yeast provides but without fermentation. In chocolate chip cookies, this results in a tender crumb with slight lift.
To ensure success, add the vinegar just before baking to maximize gas production. Avoid overmixing to retain gas bubbles. Use distilled white or apple cider vinegar for a neutral flavor.
Compared to yeast, this substitute produces a quicker rise and a more uniform texture, maintaining the classic cookie chewiness without the yeast's fermentation flavor.